Discharge device for AA battery. Homemade charger for aa batteries

Most modern gadgets are mobile devices that have compact dimensions and can work offline. To do this, they are equipped with built-in power systems, the energy source of which is a battery. The modern market offers wide choose such elements.

But small AA batteries are most widely used. However, they have a limited resource and require regular recharging. For this purpose, special devices are used that are connected to a stationary power supply. One of these devices is a charger AA batteries. It is presented on the market with various models, let’s try to choose one of the best.

What is the device

This is an electronic device with compact dimensions. It serves to charge the battery with energy from an external source. This is usually AC power.

Charger circuit for Li Ion batteries It is quite simple and therefore the device can be assembled independently. It consists of the following elements:

  • Voltage converter;
  • Rectifier;
  • Stabilizer;
  • Devices for monitoring the charging process.

A transformer is usually used as a converter, but it can be replaced by a switching power supply. To monitor the charging operation, indicators such as an LED ammeter are used.

Where are charging for AA batteries used?

The main area of ​​use of such devices is mobile gadgets. They usually run on different types of batteries. These devices are used to charge them.

But since batteries can be of different types, the characteristics of the charger for 18650 Li Ion batteries are selected in accordance with their operating voltage and rated capacity.

Design features of the device

A charger is a small gadget designed to work with specific energy sources. You can also find on sale universal devices designed for retraining both one and several batteries.

But since finger-type cells are the most popular, the most devices for charging them are produced. They are designed to work with batteries of various sizes:

Some charger models come with replacement boards designed for different types of batteries. The latest developments in this industry involve equipping the device with an adapter, which allows it to be used in any country. But some still prefer to collect Charger for AA batteries with your own hands.

Let's watch the video, types of devices, operating principles and selection aspects:

Connection to the storage network is carried out using a cord. But there are samples that are connected directly. Their use is not always convenient.

Operating principle of the device

The main purpose of such a device is to retrain the current source after the resource of their capacity has been exhausted. This process in modern memory is carried out using three modes:

  • fast charge;
  • discharge;
  • recharging.

The purpose of the first point is clear - it allows you to bring the battery into working condition. At the same time, the other two raise questions among non-professionals. However, without them, the battery may not charge.

It is these modes that are necessary to eliminate such effects as:

  • self-discharge;
  • memory effect.

The first occurs in case of prolonged non-use of the battery. In this case, contamination of the electrolyte or instability of the electrodes often occurs. The memory effect is associated with electrode manufacturing technology. And so that the current source does not fail prematurely, you should not recharge it if there is residual capacity. Therefore, the charger function includes the discharge mode.

Memory selection criteria

The purchase of such a device has its own specifics. One of the most important factors is the order in which the batteries are installed. In order not to make a mistake with the polarity and take into account all the existing features, you must carefully study the instructions and consider the drawings with options for the arrangement of elements. This will help you choose the model you need.

For example, using charging for 4 cells, you can only make a mistake with the polarity. But at the same time, when purchasing a device for 2 batteries, you will have to take into account many features of their installation.

Watch the video, criteria for choosing a charging device:

Experts advise purchasing a charger from the same manufacturer as the batteries.

When choosing a gadget, you should also pay attention to the way it is connected to the outlet. The most convenient are those that use a cord. Those connected without it often do not provide a reliable installation.

An important parameter is the charging time. By purchasing a universal charger for Li-Ion batteries Please note that the documentation provides calculated values. Wherein real time usually somewhat more and this is due to the specific operation of the device.

In addition to the parameters listed above, there is a whole list others that are no less important when choosing:

  • Number of installed batteries;
  • Standard size;
  • Features of their location;
  • Availability of protection against overheating and overvoltage;
  • Automatic shutdown when fully charged.

However, you should also take into account the fact that devices with more functions are more expensive. And in some cases you can get by with the simplest, but at the same time cheapest sample.

The best charger for AA batteries

La Crosse BC-700 and NiMN model.

A large assortment of memory devices forces you to carefully approach the choice. Which company's products should you prefer? Choose a model from a European manufacturer?

As a rule, they are of high quality, but such products are also expensive. Chargers made in China are most often items that cannot be repaired and are not reliable.

Although among these products you can find high-quality and inexpensive models. There are good chargers of domestic design. In many respects they are not inferior to foreign products, but at the same time their price is much lower.

Which model to choose depends on the specific requirements of the buyer. And to make this easier, we will look at the characteristics of devices from various manufacturers.

Let's watch a video review of the Robition Smart S100 model:

Let's start with a model branded Robition Smart S100. These are products of one of the leading domestic companies. It is a charger with two channels, equipped with a discharge button. IN the lineup This manufacturer includes devices that differ in their functionality.

For example, the Ecocharger gadget, although not capable of discharging batteries, is capable of charging even a disposable alkaline battery. Moreover, this procedure can be performed with one element up to 5 times. This function is activated by a special switch located on the side panel of the case.

In addition, the device is a 4-channel device. This means that it is able to monitor the charge level of each battery individually. Readiness is indicated LED indicator. The cost of such a device does not exceed $20.

NiMN brand chargers are more expensive. They have wider functionality and are able to discharge the battery to restore its capacity. The devices, just like the previous ones, are capable of monitoring the charge level of each individual element. The use of this device allows the battery to be restored quickly due to the high charging current. Prices for devices of this brand range from 50 to 70 dollars.

Charging model La Crosse BC-700

For more than 4 years it has served me faithfully homemade charger for charging “aa” and “aaa” batteries (Ni-Mh, Ni-Ca) with a discharge function battery to a fixed voltage value (1 Volt). The battery discharge unit was created for the possibility of carrying out CTC(Control-training cycle), to put it simply: to restore battery capacity battered by incorrect Chinese chargers with a sequential charging formula of 2 or 4 batteries. As you know, this charging method shortens the life of batteries if they are not restored in time.







Charger Specifications:

  • Number of independent charging channels: 4
  • Number of independent discharge channels: 4
  • Charge current: 250 (mA)
  • Discharge current 140 (mA)
  • Discharge 1 cut-off voltage (V)
  • Indication: LED

The charger was not assembled for an exhibition, but what is called from improvised means, that is, the surrounding goods were disposed of, which would be a pity to throw away and there was no particular reason to store.

What can you use to make your own charger for “AA” and “AAA” batteries:

  • CD-Rom case
  • Power transformer from the radio (rewind)
  • Field effect transistors with motherboards and HDD cards
  • Other components were either bought or bitten out :)

As already noted, charging consists of several nodes that can live completely autonomously from each other. That is, you can work with 8 batteries at the same time: charge from 1 to 4 + discharge from 1 to 4. The photo shows that the battery cassettes are installed under the “AA” form factor in the common people’s “pen-type batteries”; if you need to work with “mini-pen-type batteries” “AAA”, it is enough to place a small caliber nut under the negative terminal. If desired, you can duplicate it with holders for size “aaa”. The presence of a battery in the holder is indicated by an LED (the flow of current is monitored).

Charge block

Charging is carried out with a stabilized current, each channel has its own current stabilizer. In order for the charge current to remain constant when connecting both 1 and 2, 3, 4 batteries, a parametric voltage stabilizer is installed in front of the current stabilizers. Naturally, the efficiency of this stabilizer is not high and you will need to install all the transistors on the heat sink. Plan the ventilation of the case and the size of the radiator in advance, taking into account that in a closed case the temperature on the radiator will be higher than in a disassembled state. You can upgrade the circuit by introducing the ability to select the charge current. To do this, the circuit must be supplemented with one switch and one resistor for each channel, which will increase the base current of the transistor and, accordingly, increase the charge current passing through the transistor into the battery. In my case, the charge block is mounted using a hinged mounting.

Battery discharge unit


The discharge unit is more complex and requires precision in the selection of components. It is based on a comparator type lm393, lm339 or lp239, the function of which is to supply a “logical one” or “zero” signal to the gate of a field-effect transistor. When the field-effect transistor opens, it connects a load in the form of a resistor to the battery, the value of which determines the discharge current. When the battery voltage drops to the set shutdown threshold of 1 (Volts). The comparator slams shut and sets a logical zero at its output. The transistor comes out of saturation and disconnects the load from the battery. The comparator has hysteresis, which causes the load to be reconnected not at a voltage of 1.01 (V) but at 1.1-1.15 (V). You can simulate the action of the comparator by downloading. By selecting the resistor values, you can adjust the device to the voltage you need. For example: by raising the shutdown threshold to 3 Volts, you can make a discharge for li-on and Li-Po batteries.
You can it was designed to use the lm393 comparator in a DIP package. The comparators must be powered from a stabilized 5-volt source; its role is played by a TL-431 amplified by a transistor.

It all started with the fact that my camera point-and-shoot device flatly refused to work with batteries freshly removed from the charger - four AA-size NiMH batteries. Take them as usual and throw them away. But for some reason, this time curiosity prevailed over common sense (or maybe it was the toad that spoke), and I wanted to understand whether it was possible to squeeze at least something else out of these batteries. The camera is very hungry for energy, but there are also more modest consumers - wireless mice or keyboards, for example.

Actually, there are two parameters that are interesting to the consumer - the battery capacity and its internal resistance. There are also few possible manipulations - discharge and charge. By measuring the current and time during the discharge process, you can estimate the battery capacity. According to the difference in battery voltage to Idling and under load, internal resistance can be estimated. By repeating the discharge-charge cycle (i.e., performing the “training”) several times, you can understand whether this action makes sense at all.

Accordingly, the following plan was formed - we make a controlled spark gap and charger with the ability to continuously measure process parameters, perform simple arithmetic operations on the measured values, and repeat the process the required number of times. We compare, draw conclusions, and finally throw away the batteries.

Measuring stand
A complete collection of bicycles. It consists of an analog part (in the diagram below) and a microcontroller. In my case, the intellectual part was the Arduino, although this is not at all important - as long as there is the necessary set of inputs/outputs.

The stand was made from what was found within a radius of three meters. If someone wants to repeat it, it is not at all necessary to follow the diagram exactly. The choice of element parameters can be quite wide, I will comment on this a little later.

The discharge unit is a controlled current stabilizer based on op-amp IC1B (LM324N) and field-effect transistor Q1. Almost any transistor, as long as there are enough permissible voltages, currents and power dissipation. And they are all small here. Resistor feedback and at the same time part of the load (together with Q1 and R20) for the battery - R1. Its maximum value should be such as to provide the required maximum current discharge. If we assume that the battery can be discharged down to 1 V, then to ensure a discharge current of, for example, 500 mA, resistor R1 should not be larger than 2 Ohms. The stabilizer is controlled by a three-bit resistive DAC (R12-R17). Here the calculation is as follows - the voltage at the direct input of the op-amp is equal to the voltage at R1 (which is proportional to the discharge current). We change the voltage at the direct input - the discharge current changes. To scale the DAC output to the desired range, there is a trimming resistor R3. It is better if it is multi-turn. The values ​​of R12-R17 can be any (in the region of tens of kilo-ohms), the main thing is that the ratio of their values ​​is 1/2. No special accuracy is required from the DAC, since the discharge current (voltage on R1) is measured directly by the instrumentation amplifier IC1D during the process. Its gain is K=R11/R10=R9/R8. The output is fed to the microcontroller ADC (A1). By changing the values ​​of R8-R11, the gain can be adjusted to the desired value. The voltage on the battery is measured by the second amplifier IC1C, K=R5/R4=R7/R6. Why control the discharge current? The point here is basically this. If you discharge with a constant high current, then due to the large internal resistance of worn-out batteries, the permissible voltage 1 V (and there is no other reference point for stopping the discharge) will be reached before the battery actually discharges. If you discharge with a constant low current, the process will take too long. Therefore, the discharge is carried out in stages. Eight steps seemed enough to me. If the hunt is more/less, then you can change the bit depth of the DAC. In addition, by turning the load on and off, you can estimate the internal resistance of the battery. I think that the controller operation algorithm during discharge does not require further explanation. At the end of the process, Q1 is locked, the battery is completely disconnected from the load, and the controller turns on the charge unit.

Charge block. Also a current stabilizer, only uncontrolled, but switchable. The current is set by the reference voltage source on IC2 (2.5 V, accuracy 1% according to the datasheet) and resistor R21. In my case, the charge current was classic - 1/10 of the nominal battery capacity. Feedback resistor - R20. You can use any other reference voltage source - depending on your taste and availability of parts. Transistor Q2 operates in a more rigid mode than Q1. Due to the noticeable difference between Vcc and battery voltage, significant power is dissipated across it. This is the price to pay for the simplicity of the circuit. But the radiator saves the situation. Transistor Q3 serves to force Q2 to turn off, i.e., to turn off the charge unit. Controlled by signal 12 of the microcontroller. Another reference voltage source (IC3) is needed for the controller’s ADC to operate. The measurement accuracy of our stand depends on its parameters. LED1 - to indicate the process status. In my case, it does not light up during the discharge process, lights up when charging and flashes when the cycle is completed.
The supply voltage is selected to ensure that the transistors open and operate in the required ranges. In this case, both transistors have a quite high gate unlocking voltage - about 2-4 V. In addition, Q2 is “backed up” by the battery voltage and R20, so the gate unlocking voltage starts from approximately 3.5-5.5 V. In turn The LM323 cannot raise the output voltage above Vcc minus 1.5 V. Therefore, Vcc must be quite large and in my case it is 9 V.

The charge control algorithm was based on the classic version of monitoring the moment the battery voltage begins to drop. However, in reality everything turned out to be not entirely true, but more on that later.
All measured values ​​during the “research” process were written to a file, then calculations were made and graphs were drawn.

I think that with measuring stand everything is clear, so let's move on to the results.

Measurement results
So, we have charged (but non-functional) batteries, which we discharge and measure the stored capacity, and at the same time the internal resistance. It looks something like this.

Graphs on the axes: time, hours (X) and power, W (Y) for the best and worst batteries. It can be seen that the stored energy (the area under the graphs) is significantly different. In numerical terms, the measured battery capacities were 1196, 739, 1237 and 1007 mAh. Not a lot, considering that rated capacity(which is indicated on the case) - 2700 mAh. And the spread is quite large. What about internal resistance? It was 0.39, 0.43, 0.32 and 0.64 Ohm, respectively. Terrible. It is clear why the soap dish refused to work - the batteries are simply not able to deliver a large current. Well, let's start training.

Cycle one. Again the output power of the best and worst battery.

Progress is visible to the naked eye! The numbers confirm this: 1715, 1444, 1762 and 1634 mAh. The internal resistance also improved, but very unevenly - 0.23, 0.40, 0.1, 0.43 Ohm. It would seem there is a chance. But alas, further discharge/charge cycles did not yield anything. The capacitance values, as well as the internal resistance, varied from cycle to cycle within about 10%. Which lies somewhere close to the limits of measurement accuracy. Those. Long training, at least for my batteries, did nothing. But it became clear that the batteries retained more than half of their capacity and would still work at low current. At least some savings on the farm.

Now I want to dwell a little on the charging process. Perhaps my observations will be useful to someone who is planning to design a smart charger.
Here is a typical charge graph (on the left is the battery voltage scale in volts).

After the start of charging, a voltage dip is observed. In different cycles it may be greater or lesser in depth, of slightly different duration, and sometimes absent. Then, for about 10 hours, there is a uniform increase and then an almost horizontal plateau. The theory states that with a low charge current there is no voltage drop at the end of the charge. I was patient and still waited for this fall. It’s small (it’s almost invisible to the eye on the chart), you have to wait a very long time for it, but it’s always there. After ten hours of charging and before the decline, the voltage on the battery, although it increases, is extremely insignificant. This has almost no effect on the final charge; no unpleasant phenomena such as heating of the battery are observed. Thus, when designing low-current chargers, there is no point in equipping them with intelligence. A timer for 10-12 hours is enough, and no special accuracy is required.

However, this idyll was disrupted by one of the elements. After about 5-6 hours of charging, very noticeable voltage fluctuations occurred.

At first I attributed this to a design flaw in my stand. The photo shows that everything was assembled using a hinged installation, and the controller was connected with rather long wires. However, repeated experiments have shown that such nonsense consistently occurs with the same battery and never occurs with others. To my shame, I did not find the reason for this behavior. Nevertheless (and this is clearly visible on the graph) the average voltage value is growing as it should.

Epilogue

As a result, we have four batteries, which are exactly scientific methods an ecological niche has been found. We are disappointed in the capabilities of the training process. And we have one unexplained effect that occurs during charging.
Next up is a larger battery - a car battery. But there the load resistors are a couple of orders of magnitude more powerful. Somewhere they are traveling across the expanses of Eurasia.

That's all. Thank you for your attention.

I recently assembled another useless device :) It is designed to serve AA or AAA batteries - it is a discharge device with voltage control. It has two discharge modes, depending on the battery capacity. Also used as reject AA batteries, here is a convenient visualization of the voltage, since the control is carried out under load.

It is known that if you charge not completely discharged nickel-cadmium batteries, a “memory” effect appears - a decrease in the maximum capacity. To reduce the influence of this effect, it is recommended to discharge the battery to a voltage of 1 V before charging. Many expensive automatic chargers first discharge and only then charge the battery. But simple chargers do not have this function. This design and discharges two standard AA or AAA batteries.

Resistors R1 and R2, connected in series with diodes VD1 and VD2, are used as load elements for the batteries. Resistors limit the current, and diodes limit the discharge voltage, so in this device it is impossible to discharge the battery to zero.

The degree of battery discharge can be visually determined by the brightness of the HL1 LED, and you can additionally set pointer indicator voltage. The initial brightness of the glow is selected using resistor R3. Resistors - any type, power dissipation of resistors R1, R2 - 0.5 W to 1 W, R3 - 0.125 W to 0.25 W. The diodes must be silicon rectifiers with a permissible forward current of 1 A. The LED should be used in red and first checked that it shines at a voltage of 1.8..1.9 V.

With this article we are opening a new direction for our site: testing batteries and galvanic cells (or, to put it in simple language, batteries).

Despite the fact that lithium-ion batteries, specific to each specific device model, are becoming increasingly popular, the market for standard batteries general purpose is still very large - they power a lot of different products, ranging from children's toys to inexpensive cameras and professional flashes. The range of these elements is also large - batteries and accumulators different types, containers, sizes, brands, workmanship...

At first, we do not set ourselves the goal of covering all the richness of batteries - we will limit ourselves to only the most standard and widespread of them: cylindrical batteries and nickel batteries.

This article is intended to introduce you to some basic concepts regarding the batteries we study, as well as the testing methodology and equipment we use. However, we will discuss many theoretical and practical issues in subsequent articles devoted to specific batteries - especially since doing this using “live examples” is much more convenient and clearer.

Types of batteries and voltaic cells

Batteries with salt electrolyte

Batteries with a salt electrolyte, also known as zinc-carbon (however, unlike alkaline batteries, manufacturers usually simply do not indicate their chemistry on the packaging of salt batteries) are the cheapest chemical power sources available for sale: the cost of one battery ranges from four to five to eight to ten rubles, depending on the brand.


Such a battery is a zinc cylindrical container (which serves as both the body and the “minus” of the battery), in the center of which there is a carbon electrode (“plus”). A layer of manganese dioxide is placed around the anode, and the remaining space between it and the walls of the container is filled with a paste of ammonium chloride and zinc chloride diluted in water. The composition of this paste may vary: in low-power batteries it is dominated by ammonium chloride, and in higher-capacity batteries (usually designated by manufacturers as “Heavy Duty”) it is dominated by zinc chloride.

When a battery is in operation, the zinc from which its body is made gradually oxidizes, as a result of which holes may appear in it - then the electrolyte will leak out of the battery, which can lead to damage to the device in which it is installed. However, such problems were typical mainly for domestic batteries during the existence of the USSR, while modern ones are securely packaged in an additional outer shell and “leak” very rarely. However, you should not leave dead batteries in the device for a long time.

As mentioned above, the chemical composition of the electrolyte of salt batteries may vary slightly - the “high-power” version uses an electrolyte with a predominance of zinc chloride. However, the word “powerful” in relation to them can only be written in quotation marks - none of the varieties of salt batteries are designed for any serious load: in a flashlight they will last for a quarter of an hour, but in a camera they may not even be enough to extend the lens. The destiny of salt batteries is remote control remote control, watches and electronic thermometers, that is, devices whose energy consumption falls within units, in extreme cases tens of milliamps.

Alkaline batteries

The next type of battery is alkaline or manganese batteries. Some not very competent sellers and even manufacturers call them “alkaline” - this is a slightly distorted tracing paper from the English “alkaline”, that is, “lye”.


Prices for alkaline batteries vary from ten to forty to fifty rubles (however, most of their types fall into the range of up to 25 rubles, only certain models with increased power stand out), and they can be distinguished from salt ones by the inscription “Alkaline” usually present in one form or another " on the packaging (and sometimes right in the name, for example, "GP Super Alkaline" or "TDK Power Alkaline").

The negative pole of an alkaline battery consists of zinc powder - in comparison with the zinc body of salt cells, the use of powder allows you to increase the speed of chemical reactions, and therefore the current supplied by the battery. The positive pole is made of manganese dioxide. The main difference from salt batteries is the type of electrolyte: in alkaline batteries, potassium hydroxide is used as it.

Alkaline batteries are well suited for devices with power consumption from tens to several hundred milliamps - with a capacity of about 2...3 Ah they provide a very reasonable operating time. Unfortunately, they also have a significant disadvantage: high internal resistance. If you load a battery with a really high current, its voltage will drop significantly, and a significant part of the energy will be spent on heating the battery itself - as a result, the effective capacity of alkaline batteries is highly dependent on the load. Let's say, if when discharging with a current of 0.025 A we manage to get 3 A*h from the battery, then at a current of 0.25 A the actual capacity will drop to 2 A*h, and with a current of 1 A it will be completely below 1 A*h.

However, an alkaline battery can work for some time even under heavy loads, it’s just that this time is relatively short. Let's say, if a modern digital camera may not even turn on, then one set of alkaline ones will be enough for him to work for half an hour.

By the way, if you are forced to use alkaline batteries in your camera, buy two sets at once and periodically swap them, this will extend their life a little: if a battery discharged by a high current is allowed to “rest” for a while, it will partially restore its charge and will be able to work a little more. About five minutes.

Lithium batteries

The last widely used type of battery is lithium. They are typically rated at multiples of 3V, so most types lithium batteries with one and a half volt salt and alkaline are not interchangeable. Such batteries are widely used in watches, and also, less commonly, in photographic equipment.


However, there are also 1.5 V lithium batteries made in standard AA and AAA form factors - they can be used in any equipment designed for regular salt or alkaline batteries. The main advantage of lithium batteries is their lower internal resistance compared to alkaline ones: their capacity depends little on the load current. Therefore, although at low current both alkaline and lithium batteries have the same capacity of 3 A*h, if you put them in a digital camera that consumes 1 A, then the alkaline ones will “die” in about thirty minutes, but the lithium ones will live for almost three hours.

The downside of lithium batteries is their high cost: not only is lithium itself expensive, but also due to the danger of it igniting when water gets in, the design of the battery turns out to be noticeably more complex compared to alkaline ones. As a result, one lithium battery costs 100-150 rubles, that is, three to five times more expensive than a very good alkaline one. A Ni-MH battery costs about the same, it has discharge characteristics similar to lithium batteries, but can survive several hundred charge-discharge cycles - so buying lithium batteries is justified only if you have nowhere, no time or nothing to charge conventional batteries.

Yes, since we are talking about charge cycles, it must be said that it is absolutely forbidden to try to charge lithium batteries! If ordinary alkaline or salt battery when you try to charge it, it can, at most, simply leak, then sealed lithium batteries explode when charged.

Also, in addition to good discharge characteristics, lithium batteries have two more advantages, which, as a rule, are not very significant: durability (the permissible shelf life reaches 15 years, and the battery will lose only 10% of its capacity) and the ability to work at subzero temperatures, when salt batteries and alkaline batteries, the electrolyte simply freezes.

Nickel-cadmium (Ni-Cd) batteries

The main alternative to batteries are batteries - current sources, the chemical processes in which are reversible: when the battery is connected to a load, they go in one direction, and when voltage is applied to it, in the opposite direction. Thus, if after use you have to throw away the battery and buy a new one, then the battery can be charged to its full (or almost full) original capacity.

We will consider batteries used in light household electronic equipment - therefore heavy (both literally and figuratively) lead acid batteries, found in cars, uninterruptible power supplies and other devices with high power consumption and without special restrictions on weight and dimensions, are immediately left out of our article today. But we will pay much more attention to the various types of nickel batteries...

The first nickel - or, more precisely, nickel-cadmium - batteries were created by the Swedish scientist Waldmar Jungner back in 1899, but at that time they were relatively expensive, and besides, they were not sealed: when charging, the battery emitted gas. Only in the middle of the last century was it possible to create a nickel-cadmium battery with a closed cycle: the gases released during charging were absorbed by the battery itself.

Nickel-cadmium batteries are reliable and durable (they can be stored for up to five years, and charged - with proper use - up to 1000 times), they work well under low temperatures and can easily withstand high discharge currents and can be charged with both low and high currents.

However, they also have a lot of disadvantages. Firstly, a relatively low energy density (that is, the ratio of the cell’s capacity to its volume), secondly, a noticeable self-discharge current (after several months of storage, the battery will need to be recharged before use), thirdly, the use of poisonous cadmium in the design, and , fourthly, the memory effect.

It’s worth dwelling on the latter in more detail, since when we talk about batteries we will remember it more than once. The memory effect is a consequence of a violation of the internal structure of the battery: crystals begin to grow in it, reducing the effective surface and, accordingly, the battery capacity. The effect got its name due to the fact that the crystals grow especially quickly when the battery is not completely discharged: it seems to remember to what level it was discharged last time - if the battery was discharged, say, only 25%, then the next charge will restore it The capacity is not up to 100%, but less. To combat the memory effect, it is recommended to completely discharge the battery before charging - this destroys the crystals that form and restores the battery capacity. Among the available types of batteries, nickel-cadmium batteries are the most susceptible to memory effect.

However, in some cases, the use of nickel-cadmium batteries is still justified - due to their low cost, durability and the ability to charge at low temperatures without negative consequences for the battery.

Nickel metal hydride (Ni-MH) batteries

Despite their close proximity on store shelves, historically there is a gap between Ni-Cd and Ni-MH batteries: the latter were developed only in the 1980s. Interestingly, the possibility of storing hydrogen for nickel-hydrogen batteries used in space technology was initially studied, but as a result we received one of the most common types of batteries in everyday life.

Unlike nickel-cadmium batteries, nickel-metal hydride batteries do not contain heavy metals, which means they are harmless to environment and do not require special processing during disposal. However, this is far from their only advantage: from the point of view of consumers, that is, you and me, it is much more important that with the same dimensions, Ni-MH batteries have two to three times greater capacity - for the most common AA format batteries it reaches already up to 2500-2700 mA*h versus 800-1000 mA*h for nickel-cadmium.

Moreover, Ni-MH batteries also practically do not suffer from the memory effect. More precisely, manufacturers are reducing its influence year after year - and therefore, although theoretically the effect is also present in Ni-MH batteries, in practice it is insignificant in modern models. However, we will not rely on manufacturers for everything and in one of our next articles we will try to evaluate the influence of the memory effect ourselves.

Unfortunately, Ni-MH batteries have their own problems. Firstly, they have a higher self-discharge current (however, we will talk about this again a little later) compared to Ni-Cd, and secondly, although the number of recharge cycles can also reach 1000, a drop in battery capacity can be observed after 200 300 cycles; thirdly, too high discharge currents and charging at low temperatures significantly reduce the life of the battery.

Nevertheless, in terms of the totality of characteristics - cost, reliability, capacity, ease of maintenance - at the moment Ni-MH batteries are one of the best, which led to their use in a huge number of household devices.

Recently, so-called “Ready To Use” Ni-MH batteries have also appeared on sale. They differ from conventional ones in their low self-discharge current - the manufacturer assures that in six months the battery will lose no more than 10% of its capacity, and in a year - no more than 15% (for comparison, a regular Ni-MH battery will drain by 20...30% in a month, and for the year – to zero). Hence the name: being charged by the manufacturer, these batteries will not have time to completely discharge before you buy them in the store, which means they can be used without preliminary charging, immediately after purchase. The disadvantage of such batteries is their smaller capacity - an AA format cell has a capacity of 2000...2100 mAh versus 2600...2700 mAh for conventional Ni-MH batteries.

Chargers for Ni-Cd and Ni-MH batteries

Principles charge Ni-Cd and Ni-MH batteries are similar in many ways - for this reason, modern chargers, as a rule, support both types at once. Charging methods and, accordingly, types of chargers can be divided into four groups. In all cases, we will indicate the charging current through the battery capacity: for example, the recommendation to charge with a current of “0.1C” means that a battery with a capacity of 2700 mAh in such a circuit corresponds to a current of 270 mA (0.1 * 2700 = 270) , and a battery with a capacity of 1400 mAh – 140 mA.

Slow charge current 0.1C

This method is based on the fact that modern batteries can easily withstand overcharging (that is, an attempt to “fill” them with more energy than the battery can store) if the charging current does not exceed 0.1C. If the current exceeds this value, the battery may fail when overcharged.

Accordingly, a low-current charger does not need any control over the end of the charge: there is nothing wrong with its excessive duration, the battery will simply dissipate excess energy in the form of heat. Suitable chargers are cheap and widely available. To charge the battery, it is enough to leave it in such a charger for a time of at least 1.6 * C/I, where C is the battery capacity, I is the charging current. Let's say, if we take a charger with a current of 200 mA, then a battery with a capacity of 2700 mAh is guaranteed to charge in 1.6 * 2700/200 = 21 hours 36 minutes. Almost a day... in general, main drawback Such chargers are obvious - the charging time often exceeds reasonable values.

However, if you are not in a hurry, such a charger has a right to life. The main thing is if you use batteries small capacity paired with a modern charger, check that the charging current (and it must be indicated in the characteristics of the charger) does not exceed 0.1C. It is also worth considering that slow charging contributes to the memory effect of batteries.

Charging with current 0.2...0.5C without control of the end of charge

Such chargers, although rare, are still found - mainly among cheap Chinese products. At a current of 0.2...0.5C, they either do not have charge end control at all, or only have a built-in timer that turns off the batteries after a specified time.

Use similar memories absolutely not recommended: since there is no control over the end of the charge, in most cases the battery will be under- or overcharged, which will significantly shorten its life. If you save on a charger, you will lose money on batteries.

Charging current up to 1C with charge end control

This class of chargers is the most universal for everyday use: on the one hand, they charge batteries in a reasonable time (from one and a half to four to six hours, depending on the specific charger and batteries), on the other, they clearly control the end of the charge in automatic mode .

The most common method for monitoring the end of a charge is by voltage drop, usually called the “dV/dt method”, “negative delta method” or “-ΔV method”. It consists in the fact that during the entire charging, the voltage on the battery slowly increases - but when the battery reaches full capacity, it decreases briefly. This change is very small, but it is quite possible to detect it - and, having detected it, stop the charge.


Many charger manufacturers also list "microprocessor control" in their specifications - but, in essence, this is the same as negative delta control: if present, it is carried out by a specialized microprocessor.

However, voltage control is not the only one available: when the battery accumulates full capacity, the pressure and temperature of the case sharply increases, which can also be controlled. In practice, however, it is technically easiest to measure voltage, so other methods for monitoring the end of charge are rare.

Also, many high-quality chargers have two protective mechanisms: battery temperature control and a built-in timer. The first stops charging if the temperature exceeds the permissible limit, the second - if stopping the charge by negative delta did not work within a reasonable time. Both of these can happen if we use old or simply low-quality batteries.

Having finished charging the batteries with a high current, the most “reasonable” chargers continue to charge them for some time with a low current (less than 0.1C) - this allows you to get the maximum possible capacity from the batteries. The charge indicator on the device usually goes off, indicating that the main charging stage is complete.

There are two problems with such devices. Firstly, not all of them are able to “catch” the moment of voltage drop with sufficient accuracy - but, alas, this can only be verified experimentally. Secondly, although such devices are usually designed for 2 or 4 batteries, most of them do not charge these batteries independently of each other.

For example, if the instructions for the charger indicate that it can only charge 2 or 4 batteries at the same time (but not 1 or 3), this means that it has only two independent charging channels. Each of the channels provides a voltage of about 3 V, and the batteries are connected to them in pairs and in series. There are two consequences from this. The obvious thing is that you will not be able to charge a single battery in such a charger (and, say, your humble servant daily uses an mp3 player that runs on exactly one AAA battery). Less obvious is that the end of charge control is also carried out only for a couple batteries. If you use batteries that are not very new, then simply due to technological variation, some of them will age a little earlier than others - and if a pair contains two batteries with different degrees of aging, then such a charger will either undercharge one of them or overcharge the second. Of course, this will only exacerbate the rate of aging of the worse of the pair.

The “correct” charger should allow you to charge an arbitrary number of batteries - one, two, three or four - and ideally, also have a separate charging end indicator for each of them (otherwise the indicator goes out when the last battery is charged). Only in this case will you have some guarantees that each of the batteries will be charged to full capacity, regardless of the condition of the other batteries. Separate charge indicators also allow you to catch prematurely failed batteries: if out of four cells used together, one charges much longer or much faster than the others, then it is this one that will charge weak link the entire battery.

Multichannel chargers have another nice feature: in many of them, when charging half the number of batteries, you can select the charging speed. For example, the Sanyo NC-MQR02 charger, designed for four AA batteries, when charging one or two batteries, allows you to select the charging current between 1275 mA (when installing batteries in the outer slots) and 565 mA (when installing them in the central slots). When three or four batteries are installed, they are charged with a current of 565 mA.

In addition to ease of use, chargers of this type are also the most “useful” for batteries: charging with an average current with control of the end of the charge by a negative delta is optimal from the point of view of increasing the life of the batteries.

A separate subclass of fast chargers is a charger with pre-discharge of batteries. This was done to combat the memory effect and can be very useful for Ni-Cd batteries: the charger will make sure that they are first completely discharged, and only after that it will start charging. For modern Ni-MHs, such training is no longer mandatory.

Charging with a current of more than 1C with control of the end of charge

And finally, the last method is an ultra-fast charge, lasting from 15 minutes to an hour, with charge control again using a negative voltage delta. Such chargers have two advantages: firstly, you get charged batteries almost instantly, and secondly, ultra-fast charging allows you to largely avoid the memory effect.

There are, however, also disadvantages. Firstly, not all batteries can withstand fast charging well: low-quality models that have high internal resistance can overheat in this mode until they fail. Secondly, a very fast (15-minute) charge can negatively affect the life of the batteries - again, due to their excessive heating during charging. Thirdly, such a charge “fills” the battery only up to 90...95% of capacity - after which, to achieve 100% capacity, an additional charge with a low current is required (however, most fast chargers do this).

However, if you need ultra-fast battery charging, purchasing a “15-minute” or “half-hour” charger will be a good option. Of course, you should only use high-quality batteries with it. large manufacturers, as well as promptly remove used batteries from batteries.

If you are satisfied with a charge duration of several hours, then the chargers described in the previous section with charging current less than 1C and control of the end of charge using a negative voltage delta.

A separate issue is the compatibility of chargers with different types of batteries. Chargers for Ni-MH and Ni-Cd are usually universal: any of them can charge batteries of each of these two types. Chargers for Ni-MH batteries with charge termination at a negative delta voltage, even if this is not directly stated for them, can also work with Ni-Cd batteries, but on the contrary - alas. The point here is that the voltage surge, that same negative delta, is noticeably smaller for Ni-MH than for Ni-Cd, so not every charger configured to work with Ni-Cd will be able to “feel” this surge on Ni-MH .

For other types of batteries, including lithium-ion and lead-acid, these chargers are fundamentally unsuitable - such batteries have a completely different charging scheme.

Testing methodology

In the process of testing batteries and voltaic cells in our laboratory, we measure the following parameters, the most important for determining both the quality of the cells (that is, their compliance with the manufacturer's promises) and a reasonable area of ​​​​use:

capacity at various discharge modes;
the value of internal resistance;
self-discharge value (for batteries only);
presence of memory effect (only for batteries).

The main part of the test bench is, of course, an adjustable load that allows you to discharge up to four batteries at a given current at the same time.


To monitor the voltage of all four elements, a Velleman PCS10 digital recorder is used, connected to a computer via a USB interface. The measurement error is no more than 1% (the recorder’s own error is 3%, but we additionally calibrate each of its channels, making appropriate corrections to the final data), voltage measurement resolution is 12 mV, measurement frequency is 250 ms.


The installation diagram is quite simple: these are four separate current stabilizers made on the LM324 operational amplifier (this chip consists of four op-amps in one package) and IRL3502 field-effect transistors. All stabilizers are controlled by one multi-turn variable resistor, so the current on them is set simultaneously - this simplifies setting up the installation for a specific test and minimizes the error in manually setting the current. Possible load change limits are from 0 to 3 A per battery.

To measure voltage, four differential amplifiers are assembled on another LM324 chip, the inputs of which are connected directly to the contacts of the block in which the batteries are installed - this completely eliminates the error introduced by losses on the connecting wires. From the outputs of the differential amplifiers, the signal goes to the recorder.

In addition, the circuit contains a rectangular pulse generator, not shown in the figure above, that periodically turns on and then completely turns off the load. The duration of “zero” at the generator output is 6.0 s, the duration of “one” is 2.25 s. The generator allows you to test batteries in operating mode with a pulsed load and, in particular, determine their internal resistance.

Also, the figure above does not show the power supply circuit of the installation: it is connected to the computer power supply, it output voltage(+12 V) is reduced to +9 V by a stabilizer on the 78L09 chip, and the -9 V voltage required for bipolar power supply of the op-amp is generated by a capacitive converter on the ICL7660 chip. However, these are already insignificant nuances, which we discuss only in order to prevent in advance questions about the correctness of measurements that may arise from readers knowledgeable in electronics.

To cool the power transistors, feedback shunts and the actual batteries being tested, the entire installation is blown by a standard 12-volt fan of size 80x80x20 mm.


A special program was written to receive and automatically process data from the recorder - fortunately, Velleman supplies very easy-to-use SDKs and sets of libraries for many of its devices. The program allows you to plot voltage graphs on batteries in real time depending on the time elapsed since the start of the test, and also calculate – at the end of the test – their capacity. The latter is obviously equal to the product of the discharge current and the time during which the element reaches the lower voltage limit.

The boundary is selected depending on the type of element and discharge conditions. For batteries at low currents this is 1.0 V - it is simply impossible to discharge them below, as this can lead to irreversible damage to the element; at high currents the lower limit is reduced to 0.9 V in order to properly take into account the internal resistance of the battery.

For batteries, two discharge limits have practical meaning. On the one hand, an element is considered completely empty if the voltage across it drops to 0.7 V - therefore, it is logical to measure the capacity precisely after reaching this level. On the other hand, not all battery-powered devices are capable of operating at voltages below 0.9 V, so it is also of practical importance when the battery is discharged to this level. In our tests we will give both of these values ​​- although many elements, having reached the level of 1.0 V, then discharge very quickly, there are also those that stay between 0.7 V and 0.9 V for a relatively long time.

So, having installed the batteries, set the required current and turned on the recorder, we begin testing. For each type of battery, several discharge modes were selected in order to obtain the most interesting and characteristic results.

For batteries it is:

discharge with low direct current: 250 mA for AA format elements, 100 mA for AAA format;
discharge with high direct current: 750 mA for AA format elements, 300 mA for AAA format;

For Ni-MH batteries this is:

discharge with low direct current: 500 mA for AA format elements, 200 mA for AAA format;
discharge with high direct current: 2500 mA for AA format elements, 1000 mA for AAA format;
discharge with pulsed current: pulse duration 2.25 s, pause duration 6.0 s, current amplitude 2500 mA for AA format elements and 1000 mA for AAA format.

For Ni-Cd batteries of AA format, the discharge modes are the same as for Ni-MH batteries of AAA format - taking into account the similar nominal capacity of the first and second.

If when testing batteries everything is simple - I printed out the packaging, inserted the battery into the unit, started the test - then the batteries must be prepared first, because all of them, except for the "Ready To Use" series mentioned above, are completely discharged at the time of purchase. Therefore, battery testing was carried out strictly according to the following scheme;

measurement of residual capacity at low current (only for "Ready To Use" models);
charger;
high current discharge without measuring capacity (training);
charger;
high current discharge with capacity measurement;
charger;
pulsed current discharge with capacitance measurement;
charger;
low current discharge with capacity measurement;
charger;
exposure for 7 days;
low current discharge with capacity measurement - then the result is compared with that obtained in the previous step and the percentage of capacity loss due to self-discharge for 1 week is calculated;

In battery tests, we use one cell of each brand at each stage. In battery tests - at least two cells of each brand.

To charge batteries we use a Sanyo NC-MQR02 charger.


This is a fast charging charger with control of negative delta voltage and battery temperature, allowing you to charge from one to four (in arbitrary combinations) AA batteries, as well as one or two AAA batteries. The former can be charged with both a current of 565 mA and 1275 mA (if there are no more than two batteries), the latter - with a current of 310 mA per cell. Over several years of regular use, this charger has convincingly proven its high efficiency and compatibility with any batteries, which led to its choice for testing. To avoid loss of capacity due to self-discharge, in all tests except the self-discharge test itself, the batteries are charged immediately before starting measurements.


Direct current measurements give a logical picture (an example is shown in the graph above): the voltage on the elements quickly decreases in the first minutes of the test, then reaches a more or less constant level, and at the very end of the test, at the last percent of charge, quickly drops again.


Measurements using pulsed current are somewhat less commonplace. The figure above shows a greatly enlarged section of the graph obtained in such a test: voltage dips on it correspond to the load being turned on, and rises to the load being turned off. From this graph it is easy to calculate the internal resistance of the battery: as you can see, with a current amplitude of 2.5 A, the voltage sags by 0.1 V - accordingly, the internal resistance is 0.1/2.5 = 0.04 Ohm = 40 mOhm. The importance of this parameter will become clearer in our subsequent articles, in which we will compare different types of batteries and accumulators with each other - but for now we will only note that high internal resistance causes not only a voltage “dip” under load, but also a loss of energy accumulated in the batteries to heat themselves.


On a full scale, the pulses merge with each other into a continuous strip, the upper limit of which corresponds to the voltage on the battery without load, the lower limit - with load. From the shape of this strip, you can estimate not only the operating time of the element under a heavy pulse load, but also the dependence of its internal resistance on the depth of discharge: for example, as you can see, in a Sony Ni-MH battery the resistance is almost constant and begins to increase only when it is completely discharged . Good result.

As many of our readers will probably notice, we have chosen very strict discharge modes: the current of 2.5 A is very high, and the 6-second pause between pulses does not allow the element to “rest” properly (as we mentioned above, the batteries, after “resting for a while”, , can partially restore their capacity). However, this was done on purpose in order to clearly and clearly show the differences between batteries of different types and different qualities. In order to get closer to milder real operating conditions, as well as to the conditions under which battery manufacturers measure their capacity, we added discharge modes with a relatively small constant current to the testing.

By the way, manufacturers themselves usually indicate discharge modes in the same way as charging modes - in proportion to the capacity of the element. Let's say, standard measurements of battery capacity should be carried out at a current of 0.2C - that is, 540 mA for a 2700 mAh battery, 500 mA for a 2500 mAh battery, and so on. However, since batteries of the same form factor in our tests are quite similar in characteristics, we decided to test them at fixed currents that do not depend on the nameplate capacity of a particular instance - this greatly simplifies the presentation and comparison of results.

And since we are talking about capacity, it is worth mentioning some deceptiveness of such a generally accepted unit as the ampere hour. The fact is that the energy stored in the battery is determined not only by how long it held a given current, but also by what voltage it had at the same time - so, it is quite obvious that lithium battery with a capacity of 3 A*h and a voltage of 3 V is capable of storing twice as much energy as a battery with a capacity of the same 3 A*h, but with a voltage of 1.5 V. Therefore, it is more correct to indicate the capacity not in ampere-hours, but in watt-hours, receiving them through the integral of the dependence of the voltage on the battery on the discharge time at its constant current. In addition to naturally taking into account the different operating voltages of different elements, this technique also allows us to take into account how well this particular element held voltage under load. Say, if two batteries were discharged to 0.7 V in 60 minutes, but the first was at 1.1 V for most of this time, and the second at 0.9 V, it is clear that the first has a larger actual capacity - despite the fact that the final discharge time is the same. This is especially important in light of the fact that most modern electronic devices do not consume constant current, and constant power– and elements with high voltage in them will operate in more favorable modes.

Closer to practice: examples of energy consumption

Of course, in addition to abstract testing of batteries on a controlled load, we were interested in how real devices consume current. To clarify this issue, we looked around the surrounding space and randomly selected a set of objects powered by various batteries.



Only part of this set


If the device consumed more or less D.C., measurements were carried out with a conventional digital multimeter Uni-Trend UT70D in ammeter mode. If the current consumption changed significantly, we measured it by connecting a low-resistance shunt between the device and the batteries powering it, the voltage drop across which was recorded with a Velleman PCSU1000 oscilloscope.

The results are presented in the table below:


Well, among our devices there were also quite “gluttonous” ones - a flash, a camera and a flashlight with an incandescent lamp. If the latter consumed the allotted 700 mA constantly and continuously, then the nature of the energy consumption of the first two turned out to be more interesting.

The value of the vertical division in the oscillograms below is 200 mA, zero corresponds to the first division from the bottom.



Camera
Oscillogram division price – 200 mA


In normal mode, the Canon PowerShot A510, powered by two AA batteries, consumed about 800 mA - a lot, but not a record high. However, when turned on (the first group of narrow peaks on the oscillogram), lens movement (the second group of peaks) and focusing (the third group), the current could increase by more than one and a half times, up to 1.2...1.4 A. What’s interesting is that immediately After pressing the shutter, the camera's power consumption dropped - when recording a frame just taken on a flash drive, it automatically turns off the screen. However, as soon as the frame was recorded, the consumption rose back to 800 mA.



Photoflash
Oscillogram division price – 100 mA


The Pentax AF-500FTZ flash (four AA format elements) consumed current even more interestingly: it was almost zero in the periods between firings, instantly grew to 700 mA immediately after firing (this moment is captured on the oscillogram above), and then for 10. ..15 seconds smoothly decreased back to zero (the jagged line of the oscillogram was due to the fact that the flash consumes current with a frequency of about 6 kHz). At the same time, the flash demonstrated a clear relationship between the decay time of the current and the voltage of the elements supplying it: since it needed to accumulate a certain energy each time, the more the supply voltage sagged under load, the more time it took to accumulate the required reserve. This, by the way, well illustrates one of the roles of the internal resistance of batteries - the lower it is, the less, other things being equal, the voltage will drop and the faster you can take the next shot with flash.

In our next articles, where we will consider specific types and instances of batteries and accumulators, a rough idea of ​​the energy needs of different devices will help us determine which batteries are suitable for them.
If you find an error, please select a piece of text and press Ctrl+Enter.